This disclosure discusses cleaning of semiconductor wafers after the
Chemical-Mechanical Planarization (CMP) of the wafer during the
manufacturing of semiconductor devices. Disclosed is an alkaline
chemistry for the post-CMP cleaning of wafers containing metal,
particularly copper, interconnects. Residual slurry particles,
particularly copper or other metal particles, are removed from the wafer
surface without significantly etching the metal, leaving deposits on the
surface, or imparting significant contamination to the wafer while also
protecting the metal from oxidation and corrosion. Additionally, at least
one strong chelating agent is present to complex metal ions in solution,
facilitating the removal of metal from the dielectric and preventing
re-deposition onto the wafer.