The present invention relates to an optical fiber for an optical amplifier and a method for manufacturing the same, which can be applied to an optical transmission system in the S-band area (4130 nm-1530 nm). According to the present invention, silica is used as a base material and the optical fiber for an optical amplifier contains Tm3+ ions and metal ions in a first core layer formed on an inner surface of a second core layer using the MCVD (Modified Chemical Vapor Deposition) method and a solution doping method whereby the practicability and productivity of the optical fiber are remarkably improved.