An apparatus selects an access network in a mobile station capable of receiving a service from a multi-wireless communication network. The apparatus comprises a physical layer capable of communicating with the multi-wireless communication network; an access network selector for storing information on an available network in the multi-wireless communication network and selecting a network during communication and handoff; and a higher layer for providing the information stored in the access network selector to a user, and delivering selection information of a particular network in the multi-wireless communication network to the access network selector according to a method set by the user.