A method is provided for calibrating Amplitude Modulation to Phase Modulation (AM/PM) predistortion coefficients for a polynomial used to compensate for AM/PM distortion of a power amplifier in the transmit chain of a mobile terminal. In general, the power amplifier is controlled by a variable supply voltage, which is generated based on an adjustable power control signal. After the power amplifier is placed in the mobile terminal, a predetermined data pattern is transmitted in a transmit burst. During the transmit burst, the variable supply voltage is changed from a first value to a second value, and a resultant phase shift in the radio frequency output signal provided by the mobile terminal is measured. Based on the phase shift, one of numerous predetermined sets of AM/PM predistortion coefficients is selected as the AM/PM coefficients for the mobile terminal.