An ion-conductive electrolyte which comprises a compound having in the molecule a structure represented by the following chemical formula and an electrolyte salt; and a cell employing the ion-conductive electrolyte. The ion-conductive electrolyte has a low vapor pressure, has a high ion conductivity even at room temperature, and has a high lithium ion transport number. With this ion-conductive electrolyte, a highly safe cell having excellent discharge characteristics can be provided.