A radiation crosslinked (50 kGy), pressure-treated UHMWPE material has
been developed by applying compressive force on a crosslinked polymer in
a direction orthogonal to an axial direction. The deformed material is
then cooled while held in a deformed state. The resulting material is
anisotropic, with enhanced strength oriented along the axial direction.
The directionally engineered material is oxidatively stable even after
four weeks of accelerated aging in a pressure vessel containing five
atmospheres of oxygen (ASTM F2003). Because of its oxidative stability,
the deformation processed material is a suitable candidate for
air-permeable packaging and gas sterilization, which has thus far been
reserved for remelted highly crosslinked UHMWPEs.