Catalysts for oxidation of methanol to formaldehyde, comprising a catalytic mixtures of Fe.sub.2(MoO.sub.4).sub.3/MoO.sub.3, wherein the Mo/Fe atomic ratio ranges from 1.5 to 5, and a compound of cerium molybdenum and oxygen in a quantity from 0.1 to 10% by weight expressed as cerium.

 
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