The present invention concerns solvent-based acrylic pressure sensitive
adhesives and hot melt (or solvent-less) acrylic pressure sensitive
adhesives comprising a solution or misible blend of a. at least one
hydrophobic (meth) acrylic polymer, b. at least one substantially water
insoluble polyol having a number average molecular weight of from 1,000
to 20,000 and selected from the group consisting of polyester polyols,
acrylic polyols, polycarbonate polyols and polyether polyols, c. at least
one transition metal complex as cross-linking agent, d. optionally one or
more tackifying resins, g. optionally one or more solvents, h. optionally
one or more of plasticizers, adhesion promoters, pigments, fillers,
antioxidants and UV stabilizers. It employs polyols which are
substantially insoluble in water and miscible with the acrylic polymer
used in the adhesive composition.