The disclosure relates to a process for preparing butadiene. The process
involves nonoxidatively catalytically dehydrogenating butane to obtain a
product gas stream containing butane, 1-butene, 2-butene, butadiene,
hydrogen and secondary constituents. The 1-butene and 2-butene of the
product gas stream is then oxidatively dehydrogenated to give a second
gas stream containing butane,2-butene, butadiene, hydrogen, steam and
secondary constituents. Next, the butane,2-butene and butadiene are
separated from the second gas stream and the butane and 2-butene are then
separated from the butadiene product. The butane and 2-butene are then
recycled into the nonoxidative catalytic dehydrogenating zone.