A large-scale and efficient industrialization of olefin polymerization by
metallocene catalysts is realized by, in olefin polymerization by
metallocene-based catalysts, increasing catalytic activity and
polymerization efficiency to sufficiently bring out the performances of
the metallocene catalysts and maintain a stable polymerization reaction.
The amount of a halogen-containing compound is controlled so that the
gram-atomic amount ratio to a transition metal of a halogen atom in a
halogen-containing compound in solvents and materials other than a
halogen atom in a catalyst component is 0.8 or less, in manufacturing
plants of commercial level in an olefin polymerization by a metallocene
catalyst.