The present invention concerns an optical fiber 10 comprising a substantially pure silica glass core 12, a concentric tin-doped core/cladding interface region 14, and a concentric fluorine-doped depressed cladding layer 16. The tin-doped core/cladding interface region 14 comprises a low concentration gradient of tin dioxide, which advantageously results in a de minimis refractive index change, resistance to hydrogen incursion, and thermal stability of any fiber Bragg gratings written into the interface region 14.