A conducting material comprising: a conducting core region comprising
copper and from 0.001 atomic percent to 0.6 atomic percent of one or more
metals selected from iridium, osmium and rhenium; and an interfacial
region. The interfacial region comprises at least 80 atomic percent or
greater of the one or more metals. The invention is also directed to a
method of making a conducting material comprising: providing an
underlayer; contacting the underlayer with a seed layer, the seed layer
comprising copper and one or more metals selected from iridium, osmium
and rhenium; depositing a conducting layer comprising copper on the seed
layer, and annealing the conducting layer at a temperature sufficient to
cause grain growth in the conducting layer, yet minimize the migration of
the one or more alloy metals from the seed layer to the conducting layer.
The method further comprises polishing the conducting layer to provide a
polished copper surface material, and annealing the polished copper
surface material at a temperature to cause migration of the one or more
metals from the seed layer to the polished surface to provide an
interfacial region in contact with a copper conductor core region. The
interfacial region and the copper conductor core region comprise the one
or more metals.