A method for making a doped magnesium diboride powder is provided. The method includes coating a polymeric precursor on at least one of a plurality of particles of a first phase, where the first phase includes a magnesium diboride powder, where the polymeric precursor includes chemical elements yielding a second phase. The second phase includes one or more of a boride, a nitride, a carbide, an oxide, an oxy-boride, an oxy-nitride, an oxy-carbide, or combinations thereof. The method further includes forming a second phase coating onto at least one of the plurality of particles of the magnesium diboride powder.