A method for alteration of the morphology of cellulose fibers,
particularly softwood fibers, by (a) subjecting the fibers to a metal
ion-activated peroxide treatment carried out at a pH of between about I
and about 9, preferably between 3 and 7, and (b) subjecting the treated
fibers to a refining treatment thereby converts SW fibers to HW-like
fibers in many respects. The metal ion-activated peroxide treatment has
been noted to act on pulp cellulose and hemi-cellulose, causing oxidation
and oxidative degradation of cellulose fibers. The chemical treatment of
the pulp, taken alone, is not sufficient to attain the desired
modification of the morphology of the fibers, however, subsequent
refining or like mechanical treatment of the chemically-treated fibers to
achieve a given degree of refinement of the fibers requires dramatically
less refining energy to achieve a desired end point of refinement and to
impart other desirable properties to the pulp. A pulp of modified SW
fibers and a mixture of HW fibers and modified HW fibers are disclosed.