Use of metal complex compounds of formula [L.sub.nMe.sub.mX.sub.p].sup.zY.sub.q (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper,X is a coordinating or bridging radical,n and m are each independently of the other an integer having a value of from 1 to 8,p is an integer having a value of from 0 to 32,z is the charge of the metal complex,Y is a counter-ion,q=z/(charge Y), andL is a ligand of formula ##STR00001## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 are each independently of the others hydrogen; unsubstituted or substituted C.sub.1-C.sub.18alkyl or aryl; cyano; halogen; nitro; --COOR.sub.12 or --SO.sub.3R.sub.12 wherein R.sub.12 is in each case hydrogen, a cation or unsubstituted or substituted C.sub.1-C.sub.18alkyl or aryl; --SR.sub.13, --SO.sub.2R.sub.13 or --OR.sub.13 wherein R.sub.13 is in each case hydrogen or unsubstituted or substituted C.sub.1-C.sub.18alkyl or aryl; --N(R.sub.13)--NR'.sub.13R''.sub.13 wherein R.sub.13, R'.sub.13 and R''.sub.13 are as defined above for R.sub.13; --NR.sub.14R.sub.15 or --N.sup..sym.R.sub.14R.sub.15R.sub.16 wherein R.sub.14, R.sub.15 and R.sub.16 are each independently of the other(s) hydrogen or unsubstituted or substituted C.sub.1-C.sub.18alkyl or aryl, or R.sub.14 and R.sub.15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms;with the proviso that R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 are not simultaneously hydrogen, as catalysts for oxidation reactions,and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

 
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