A method and apparatus for growing low defect, optically transparent,
colorless, crack-free, substantially flat, single crystal Group III
nitride epitaxial layers with a thickness of at least 10 microns is
provided. These layers can be grown on large area substrates comprised of
Si, SiC, sapphire, GaN, AlN, GaAs, AlGaN and others. In one aspect, the
crack-free Group III nitride layers are grown using a modified HVPE
technique. If desired, the shape and the stress of Group III nitride
layers can be controlled, thus allowing concave, convex and flat layers
to be controllably grown. After the growth of the Group III nitride layer
is complete, the substrate can be removed and the freestanding Group III
nitride layer used as a seed for the growth of a boule of Group III
nitride material. The boule can be sliced into individual wafers for use
in the fabrication of a variety of semiconductor structures (e.g., HEMTs,
LEDs, etc.).