A method of modifying reformate gas composition downstream of the reformer
so that it remains in a carbon-free region, i.e. above the critical
oxygen/carbon ratio even at the desired minimum operating temperature.
This is accomplished by using staged partial oxidation in a partial
oxidation chamber downstream of the reformer. A small amount of air (or
oxygen) is added. The net result is an increase in the oxygen/carbon
ratio and, thus, a lowering of the required temperature for soot-free
operation. Immediately downstream of this partial oxidation chamber, heat
can be removed to cool the gas prior to a second stage of partial
oxidation. A second stage partial oxidation chamber produces additional
water and further increases the oxygen/carbon ratio and further lowers
the required gas temperature for soot-free operation. Further stages of
partial oxidation followed by cooling of the gas can be repeated until
the oxygen/carbon ratio is sufficiently high to allow soot-free operation
at the lowest required operating temperature.