A multi-domain vertical alignment liquid crystal display panel, a thin film transistor array, and methods of fabrication the same are provided. The TFT array substrate comprises a substrate, data lines, scan lines and pixel structures. The data lines and the scan lines are arranged on the substrate to define a plurality of pixel regions. Each pixel structure is arranged in the corresponding pixel region. Each pixel structure comprises a TFT, a pixel electrode and a dielectric lining layer. The TFT is electrically connected to the corresponding data line and the corresponding scan line. The pixel electrode having slits is placed upon the TFT and is electrically connected thereto. The dielectric lining layer is disposed on the substrate. Part of the dielectric lining layer is sandwiched between the pixel electrode and the substrate, to make the liquid crystal molecules inside the liquid crystal display have more tilt directions.