The invention relates to a carbon-carbon bond creation method comprising the coupling of a transferable group and an acceptor group. The inventive method comprises the following steps: a) activation of a siliceous compound bearing a transferable group by an activation agent; b) addition of an acceptor group-bearing derivative; and, simultaneously or in any consecutive order, c) addition of a palladacycle-type compound acting as a catalyst of the coupling reaction between the transferable group and the acceptor group with the creation of the carbon-carbon bond.