This cumene process involves contacting, in an alkylation zone, a first
benzene recycle stream and a propylene feed stream with an alkylation
catalyst to form cumene. In a transalkylation zone, a
polyisopropylbenzene recycle stream and a second benzene recycle stream
are contacted with a transalkylation catalyst to form additional cumene.
The effluents are passed into a benzene distillation column. From the
benzene distillation column, a first benzene recycle stream is removed as
overhead; a second benzene recycle stream is removed as a side draw; and
a bottoms stream comprising polyisopropylbenzene, cumene, and heavy
aromatics is removed from an end. The bottoms stream is passed to a
dividing wall distillation column where the polyisopropylbenzene recycle
stream is removed from an intermediate point; a cumene product stream is
removed from a first end, and a heavy aromatic stream is removed from a
second end.