An ion trap (104) for a mass spectrometer includes an RF trapping voltage
source (112) for applying an RF trapping voltage to at least one of a
plurality of electrodes (102, 106, 110) of the ion trap (104) to trap at
least a portion of ions in the ion trap (104); a resonance excitation
voltage source (114) for applying a resonance excitation voltage pulse to
the electrodes(102, 106, 110) to cause at least a portion of a selected
set of ions to undergo collisions and break into ion fragments; and a
computer (116) for controlling the RF trapping voltage source (112) to
reduce the RF trapping voltage after a predetermined delay period
following termination of the resonance excitation voltage pulse to a
second amplitude for retaining a low mass ion fragments in the ion trap
(104) for later analysis.