An apparatus removes carbon monoxide (CO) from a hydrogen-rich gas stream
in a hydrogen fuel cell system. CO fouls costly catalytic particles in
the membrane electrode assemblies of proton exchange membrane (PEM) fuel
cells. A vessel houses a carbon monoxide adsorbent. The vessel may be a
rotating pressure swing adsorber. A water gas shift reactor is upstream
of the rotating pressure swing adsorber. The water gas shift reactor may
include a second adsorbent adapted to adsorb carbon monoxide at low
temperatures and to desorb carbon monoxide at high temperatures. The
apparatus advantageously eliminates the use of a preferential oxidation
(PROX) reactor, by providing an apparatus which incorporates CO
adsorption in the place of the PROX reactor. This cleans up carbon
monoxide without hydrogen consumption and the concomitant, undesirable
excess low grade heat generation. The present invention reduces start-up
duration, and improves overall fuel processor efficiency during normal
operation.