A method for forming a strained metal nitride film and a semiconductor
device containing the strained metal nitride film. The method includes
exposing a substrate to a gas containing a metal precursor, exposing the
substrate to a gas containing a silicon precursor, exposing the substrate
to a gas containing a nitrogen precursor activated by a plasma source at
a first level of plasma power and configured to react with the metal
precursor or the silicon precursor with a first reactivity
characteristic, and exposing the substrate to a gas containing the
nitrogen precursor activated by the plasma source at a second level of
plasma power different from the first level and configured to react with
the metal precursor or the silicon precursor with a second reactivity
characteristic such that a property of the metal silicon nitride film
formed on the substrate changes to provide the strained metal silicon
nitride film.