A polymerization process for producing a tetrafluoroethylene copolymer,
and the copolymer produced thereby, are provided. The copolymer is of the
dispersion/fine powder type and contains polymerized tetrafluoroethylene
monomer units and co-polymerized higher homologous comonomer units having
the formula (C.sub.nF.sub.(2n+1))CH.dbd.CH.sub.2, wherein
6.ltoreq.n<10, in which the primary particles are believed to have a
core and shell structure and the polymerized comonomer units are present
in an amount from 0.01 mol % to 0.3 mol %, based upon total copolymer
composition. The copolymer has a raw dispersion primary particle size
(RDPS) of less than 0.210 microns coupled with a standard specific
gravity (SSG) of less than 2.143. Preferably the copolymer has comonomer
units present in an amount from 0.05 mol % and 0.25 mol % and the RDPS is
within the range between 0.178 microns and 0.200 microns, coupled with a
SSG of less than 2.140. Copolymers produced according to the invention,
(perfluorohexyl)ethylene (PFHE) and (perfluorooctyl)ethylene (PFOE), may
be shaped into the form of 0.1 inch diameter expanded beading, which
expanded beading can have a break strength of at least 10.0 lbs, and
which may exceed 13.0 lbs.