A catalyst for selective hydrogenation of acetylenes and diolefins,
particularly in a raw gas feed stream for front end selective
hydrogenation. The catalyst contains a low surface area carrier with a
surface area from about 2-20 m.sup.2/g, wherein the pore volume of the
pores of the carrier is greater than about 0.4 cc/g, wherein at least 90
percent of the pore volume of the pores is contained within pores having
a pore diameter greater than about 500 .ANG. and wherein from about 1 to
about 2 percent of the total pore volume is contained in pores with a
pore diameter from about 500 to about 1,000 .ANG., palladium, wherein the
palladium comprises from about 0.01 to about 0.1 weight percent of the
catalyst, and a Group IB metal, wherein the Group IB metal comprises from
about 0.005 to about 0.06 weight percent of the catalyst.