The present invention relates to a hybrid battery module, which comprises: a first cell set; a first programmable fuse; a first discharging switch; a first charging switch; a first analog front end circuit; a first thermister; a second cell set; a second programmable fuse; a second discharging switch; a second charging switch; a second analog front end circuit; a second thermister; and a controller; whereby the voltage of the first cell set and the second cell set can reach a balance status when the hybrid battery module is disposed into a jig; When the voltage of the first cell set and the second cell set are balanced, then the battery pack can parallel charging/discharging the first cell set and the second cell set simultaneously. Furthermore, the present invention also provides a method for manufacturing the hybrid battery module and its charging and discharging method.