The present invention relates to an atmospheric pressure, reactive
separation column packed with a solid acid zeolite catalyst for producing
cumene from the reaction of benzene with propylene. Use of this
un-pressurized column, where simultaneous reaction and partial separation
occur during cumene production, allow separation of un-reacted, excess
benzene from other products as they form. This high-yielding,
energy-efficient system allows for one-step processing of cumene, with
reduced need for product purification. Reacting propylene and benzene in
the presence of beta zeolite catalysts generated a selectivity greater
than 85% for catalytic separation reactions at a reaction temperature of
115 degrees C and at ambient pressure. Simultaneously, up to 76% of
un-reacted benzene was separated from the product; which could be
recycled back to the reactor for re-use.