A polysilane composition characterized as containing a polysilane compound and a silicone compound in the ratio (polysilane compound:silicon compound) by weight of 80:20-5:95, and also containing an organic peroxide in the amount of 1-30 parts by weight, based on 100 parts by weight of the polysilane compound and silicone compound, wherein the silicone compound contains 40-100% by weight of a double bond containing silicon compound.