There is disclosed a process for producing a catalyst. The process
includes the steps of: a) combining a dendrimer polymer and metal salt in
solution forming a metal ion complex; b) exposing the metal ion complex
to a reducing environment forming a dendrimer metal nanocomposite; c)
depositing the dendrimer metal nanocomposite onto a catalyst support
material; d) removing a solvent from the dendrimer metal nanocomposite
forming metal clusters; and e) removing the dendrimer polymer forming a
catalyst. Additionally, there is disclosed a catalyst having a catalytic
metal deposited on a substrate. The catalytic metal is formed in clusters
having a size of from 2 to 150 atoms. In another aspect, the clusters may
have a spacing of from 2 to 100 nanometers between adjacent metal
clusters. Further, in another aspect, the metal clusters which comprise
the catalyst have a size distribution in which 70% of the clusters are
within 0.6 nm of the average diameter and 99% of the particles are within
1.5 nm of the average diameter.