The present invention relates to a method for producing a phosphoric acid
ester-based polymer, including copolymerizing a monomer 1 represented by
the following formula (1), a monomer 2 represented by the following
formula (2), and a monomer 3 represented by the following formula (3), at
pH 7 or lower, in the present of a polymerization solvent having a
dissolved oxygen concentration at 25.degree. C. of 0.01 to 4.0 mg/kg. The
invention also relates to a method for producing a phosphoric acid
ester-based polymer, including copolymerizing the monomers 1, 2 and 3 at
pH 7 or lower, in the presence of a phosphonic acid-based chelating
agent. The invention also relates to a method for producing a phosphoric
acid ester-based polymer from a mixed solution containing the monomer 1,
2 and 3, including obtaining a mixed solution by mixing the monomers 1 to
3 at a temperature of 10 to 50.degree. C., initiating a polymerization
within 72 hours after the mixing of the monomers 1 to 3, and maintaining
the temperature of the mixed solution in the range of 10 to 50.degree. C.
until the polymerization is initiated:
##STR00001##
wherein R.sup.1 and R.sup.2 each represent a hydrogen atom or a methyl
group; and R.sup.3 represents a hydrogen atom or --COO(AO).sub.nX
[wherein AO represents an oxyalkylene group or oxystyrene group having 2
to 4 carbon atoms; n represents an average number of added moles of AO,
and is a number from 3 to 200; and X represents a hydrogen atom or an
alkyl group having 1 to 18 carbon atoms],
##STR00002##
wherein R.sup.4 represents a hydrogen atom or a methyl group; R.sup.5
represents an alkylene group having 2 to 12 carbon atoms; m1 represents a
number from 1 to 30; and M represents a hydrogen atom, an alkali metal or
an alkaline earth metal, and
##STR00003##
wherein R.sup.6 and R.sup.8 each represent a hydrogen atom or a methyl
group; R.sup.7 and R.sup.9 each represent an alkylene group having 2 to
12 carbon atoms; m2 and m3 each represent a number from 1 to 30; and M
represents a hydrogen atom, an alkali metal or an alkaline earth metal.