A composite of glass and hot melt composition including glass; a primer layer formed on the glass using a primer containing a film forming resin and at least one alkoxysilyl group-containing compound selected from the group consisting of isocyanate silane and a reaction product of aminosilane and epoxysilane; and a hot melt layer formed on the primer layer using a hot melt composition containing an aromatic polyester (a), and its production method are provided. The resulting composite of glass and hot melt composition is excellent in water-resistant adhesion to glass.