An engine exhaust catalyst containing precious metal nanoparticles is
promoted with bismuth. The bismuth promotion improves the catalyst's CO
oxidation performance. Also, by varying the amount of bismuth that is
added, the NO conversion rate that can be realized with the catalyst can
be controlled. The control over the NO conversion rate is important
because the passive regenerative performance of a particulate filter used
in engine exhaust systems is based on the amount NO.sub.2 that is present
in the exhaust stream that reaches the particulate filter. The amount of
NO.sub.2 being produced needs to be optimized (not necessarily maximized)
so that adequate particulate filter regeneration performance can be
maintained while avoiding unused, toxic NO.sub.2 from being exhausted
into the atmosphere.