An improved process for the manufacture of ethylene oxide through the
epoxidation of ethylene using a catalyst comprising silver and at least
one efficiency-enhancing salt of a member of a redox-half reaction pair.
Added to the epoxidation reaction is a two-component gas-phase promoter
system comprising a chlorine-containing component (for example ethyl
chloride, methyl chloride, vinyl chloride and ethylene dichloride), and a
nitrogen-containing component of nitric oxide and other compounds capable
of generating under reaction conditions at least one gaseous
efficiency-enhancing member of a redox-half reaction pair comprising NO,
NO.sub.2, N.sub.2O.sub.3 or N.sub.2O.sub.4. The amount of each component
of said gaseous promoter is adjusted to maintain the ration of N* to Z*
less than or equal to 1 wherein, N* is the nitric oxide equivalent in
ppmv, ranging from 1 to 20 ppmv and Z*=ethyl chloride equivalent
(ppmv)*100 percent/ethane equivalent (mol percent)*100 ranging from 5 to
40 ppmv.