This disclosure relates to a process of manufacturing para-xylene,
comprising (a) contacting a pygas feedstock and methylating agent with a
catalyst under reaction conditions to produce a product having
para-xylene, wherein the product has higher para-xylene content than the
para-xylene content of the pygas feedstock; and (b) separating the
para-xylene from the product of the step (a), wherein the catalyst
comprises a molecular sieve having a Diffusion Parameter for
2,2-dimethylbutane of about 0.1-15 sec.sup.-1 when measured at a
temperature of 120.degree. C. and a 2,2-dimethylbutane pressure of 8
kPa-a and the pygas comprises from about 1 to about 65 wt % benzene and
from about 5 to 35 wt % toluene.