Methods of producing vinyllactam copolymers which include: providing at
least one water-soluble N-vinyllactam; providing at least one hydrophobic
comonomer; and subjecting the at least one water-soluble N-vinyllactam
and the at least one hydrophobic comonomer to free-radical polymerization
in an organic solvent in the presence of an initiator, under a
combination of process measures selected from the group consisting of A
and B; wherein: (A) comprises (i) polymerization under reflux, and at
least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii)
comprises an addition of at least 5 mol % of N-vinyllactam to the
polymerization mixture if at least 70 mol % of the total amount of
hydrophobic monomer used have completely reacted, (iii) comprises return
of condensate formed in the reflux from below to the polymerization
mixture, (iv) comprises introduction of the initiator in the form of a
solution in an organic solvent from below into the polymerization
mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi)
comprises distilling off a portion of the organic solvent and continuing
the polymerization following conversion of 70 to 99% by weight of the
N-vinyllactam used, and (vii) comprises introduction of at least one
monomer from below into the polymerization mixture; and wherein (B)
comprises (viii) polymerization under a superatmospheric pressure such
that vaporization of the polymerization components is avoided, and at
least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the
proviso that a combination of (viii) with any of (i), (iii) or (v) is
carried out sequentially.