According to the present invention, aqueous multi-stage polymer
dispersions comprising an acid-functional first polymer and an
epoxy-functional second polymer, wherein 90 mole % or more of the said
epoxy groups, based on the moles of epoxy groups in the monomer mixture
used to form the second polymer, are retained in the aqueous dispersion
after said dispersion is stored in a sealed container for 10 days at
60.degree. C. Further, methods of making the aqueous multistage polymer
dispersion comprise polymerizing the monomers used to make the second
polymer in the presence of an aqueous dispersion of the first polymer.
Preferably, the second polymer is formed in the presence of 0.3 wt. % or
less, based on the total weight of the first polymer and the ingredients
to form the second polymer, of one or more strong acid surfactant, and 3)
0.1 wt. % or less, based on the total weight of the first polymer and the
ingredients to form the second polymer, of one or more initiator that
contains strong acid groups or generates strong acid groups under the
conditions of aqueous emulsion polymerization. The aqueous dispersions
provide non-toxic, odor free storage stable coating compositions that
form coatings having excellent film toughness and hardness.