Resin beads having an average particle size of from 0.001 mm to 10 mm and
containing a continuous phase and a particulate dispersed phase are
described. The continuous phase includes elastomeric polymers; the
dispersed phase includes homopolymers and/or copolymers containing repeat
units resulting from the polymerization of one or more aryl polymerizable
monomers. The unexpanded polymer resin beads can be prepared by
dispersing an organic phase containing elastomeric polymers and one or
more monomers, into droplets and polymerizing the monomers in the organic
droplets in a low shear flow pattern. The beads can be impregnated with
blowing agents, expanded and can be used to make molded articles. Resin
beads having a continuous phase comprising a nitrile rubber, and a
dispersed phase comprising one or more homopolymers and/or copolymers
containing repeat units resulting form the polymerization of one or more
aryl polymerizable show prolonged retention of blowing agents in
unexpanded form.