The present invention discloses a method, apparatus and method of
manufacturing an apparatus; all to produce hydrogen gas, particularly
synthesis gas. Preferred embodiments of the invention include an alpha
alumina membrane which has been treated with a TiO.sub.2 wash coat on one
side and has an active gamma alumina layer on an opposite side. A metal
catalyst, preferably rhodium, is deposited within the pores of the
alumina. Oxygen travels through the membrane and is activated before
contacting methane on the other side of the membrane and forming
synthesis gas through partial oxidation of the methane. Embodiments of
the invention have a number of benefits including the high conversion
rate of oxygen (100%), the separate feed streams of methane and oxygen
which allow for optimal ratios to be used without danger of explosion,
and the opportunity to vary the feed rates without changing the products
formed. Normally gaseous hydrocarbons recovered from remote oil wells
(e.g. offshore oil wells) can thus be converted to synthesis gas and then
to normally liquid hydrocarbons via a Fischer-Tropsch type reaction. The
normally liquid hydrocarbons are easier to transport away from the remote
oil well than normally gaseous hydrocarbons.