A cast stainless steel alloy and articles formed therefrom containing
about 0.5 wt. % to about 10 wt. % manganese, 0.02 wt. % to 0.50 wt. % N,
and less than 0.15 wt. % sulfur provides high temperature strength both
in the matrix and at the grain boundaries without reducing ductility due
to cracking along boundaries with continuous or nearly-continuous
carbides. Alloys of the present invention also have increased nitrogen
solubility thereby enhancing strength at all temperatures because nitride
precipitates or nitrogen porosity during casting are not observed. The
solubility of nitrogen is dramatically enhanced by the presence of
manganese, which also retains or improves the solubility of carbon
thereby providing additional solid solution strengthening due to the
presence of manganese and nitrogen, and combined carbon. Such solution
strengthening enhances the high temperature precipitation-strengthening
benefits of fine dispersions of NbC. Such solid solution effects also
enhance the stability of the austenite matrix from resistance to excess
sigma phase or chrome carbide formation at higher service temperatures.
The presence of sulfides is substantially eliminated.