The invention relates to a spray-dried powder formulation comprising
particles that contain the following components i) to iii): i) a compound
of formula 1, in which A represents a group selected from (I), (II) or
(III), R and R' each representing hydrogen or in combination form a group
selected from a single bond, --CH.sub.2-- and --O--, and in which X.sup.-
represents a negatively charged anion, ii) at least one embedding
material selected from the group consisting of mono- or disaccharides,
oligosaccharides, polymers, sugar alcohols and cholesterol, iii) an
organic, physiologically acceptable, sterically demanding acid, selected
from the group consisting of ascorbic acid, a monovalent, divalent or
trivalent carboxylic acid, preferably fumaric acid, oxalic acid, diacetic
acid or a sterically demanding amino acid and a fruit acid or culinary
acid, preferably citric acid, tartaric acid, malic acid, lactic acid,
acetic acid, .alpha.-hydroxycaprylic acid or gluconic acid. The invention
also relates to a method for producing said formulation and to the use of
an organic, physiologically acceptable, sterically demanding acid, from
the group consisting of ascorbic acid, a fruit acid or culinary acid,
preferably citric acid, tartaric acid, malic acid, lactic acid, acetic
acid, .alpha.-hydroxycaprylic acid or gluconic acid and a monovalent,
divalent or trivalent carboxylic acid, preferably fumaric acid, oxalic
acid, diacetic acid or a sterically demanding amino acid, for stabilising
a powder formulation produced by spray-drying containing the
aforementioned compound i) of formula 1 and a suitable embedding material
ii).