Process for the manufacture of 1,2-dichloroethane starting with a
hydrocarbon source according to which: a) the hydrocarbon source is
subjected to a first cracking step, namely a pyrolysis step performed in
a cracking oven, thus producing a mixture of cracking products; b) the
said mixture of cracking products is subjected to a succession of
treatment steps ending with a drying step which makes it possible to
obtain a mixture of products containing ethylene and other constituents;
c) the said mixture of products containing ethylene derived from step b)
is separated into at least one fraction containing ethylene and into a
heavy fraction; d) the fraction(s) containing the ethylene is (are)
conveyed to a chlorination reactor and/or to an oxychlorination reactor,
in which reactors most of the ethylene present is converted to
1,2-dichloroethane; e) the 1,2-dichloroethane obtained is separated from
the streams of products derived from the chlorination and oxychlorination
reactors; the process being characterized in that a step for
hydrogenating the acetylene is carried out upstream of the drying step
ending the succession of treatment steps constituting step b) and/or on
at least one of the fractions containing ethylene after separation during
step c).