Disclosed are processes for preparing polyareneazole polymers that include
contacting, in polyphosphoric acid, azole-forming monomers and metal
powder, the metal powder added in an amount of from about 0.05 to about
0.9 weight percent, based on the total weight of the azole-forming
monomers, and reacting the azole-forming monomers to form the
polyareneazole polymers. Polyareneazoles, filaments and yarns are also
disclosed.