A process for preparing a fluoropolymer dispersion that is substantially
anionic fluorinated surfactant free includes adding to a fluoropolymer
dispersion a nonionic surfactant having a cloud point (CP) between 40 and
80.degree. C. in a concentration of 1.5% to 50% by weight of the
fluoropolymer, heating the dispersion up to a temperature T.sub.c in a
range of CP.+-.10.degree.C., decanting the dispersion in a reactor at
T.sub.c until obtaining a lower aqueous phase containing a concentrated
fluoropolymer dispersion and an upper aqueous phase substantially not
containing the fluoropolymer dispersion, washing the decanted dispersion
with a solution of water and nonionic surfactant having a concentration
of the nonionic surfactant of 0.5% to 50% by weight of the fluoropolymer,
removing the upper aqueous phase from the upper part of the reactor, and
discharge and recovery of the fluoropolymer dispersion.