A method produces acetic acid by continuously reacting methanol with
carbon monoxide in the presence of a rhodium catalyst, an iodide salt,
methyl iodide, methyl acetate, and water; and thereby producing acetic
acid at a production rate of 11 mol/Lhr or more while keeping the
acetaldehyde content of a reaction mixture to 500 ppm or less, in which
the reaction is carried out at a carbon monoxide partial pressure in a
gaseous phase of a reactor of 1.05 MPa or more and/or at a methyl acetate
content of the reaction mixture of 2 percent by weight or more to thereby
keep the production rate of acetaldehyde to 1/1500 or less that of acetic
acid. This method can reduce production of by-products without reducing
the reaction rate of acetic acid even at a low water content and a low
hydrogen partial pressure in a reaction system.