Optical devices with versatile spectral attributes are provided that are implemented with one or more modulated and homogeneous layers to realize leaky-mode resonance operation and corresponding versatile spectral-band design. The first and/or higher multiple evanescent diffraction orders are applied to excite one or more leaky modes. The one- or two-dimensional periodic structure, fashioned by proper distribution of materials within each period, can have a resulting symmetric or asymmetric profile to permit a broadened variety of resonant leaky-mode devices to be realized. Thus, the attributes of the optical device permit, among other things, adjacent, distinct resonance frequencies or wavelengths to be produced, convenient shaping of the reflection and transmission spectra for such optical device to be accomplished, and the wavelength resonance locations to be precisely controlled so as to affect the extent to which the leaky modes interact with each other. Further, the profile asymmetry allows for the precise spectral spacing at interactive leaky modes so as to provide greater flexibility in optical device design.