A method is disclosed for producing polyvinyl chloride which includes
mixing a vinyl chloride solution with an initiator solution in at least
one high shear mixing device comprising at least one rotor/stator set
producing a rotor tip speed of at least 5.1 m/sec (1000 ft/min), to form
a polymerization mixture; and allowing the mixture to polymerize by free
radical polymerization to form polyvinyl chloride. The polymerization
mixture may be subjected to free radical polymerization conditions
comprising a temperature in the range of about 20.degree. C. to about
230.degree. C. In some embodiments, the high shear mixing device produces
a shear rate of at least 20,000 s.sup.-1. A system for carrying out the
method is also disclosed.