The process of the present invention comprises a first step in which crude
molten bisphenol A containing phenol is supplied to a flash evaporator
and separated into a gaseous phase comprising phenol and a liquid phase
comprising bisphenol A and residual phenol, and a second step in which
the liquid phase obtained in the first step is heated by a thin film
evaporator and separated into a gaseous phase comprising phenol and a
liquid phase comprising concentrated bisphenol A and residual phenol,
part of the liquid phase obtained in the second step being circulated to
the first step and supplied to the flash evaporator along with crude
molten bisphenol A. It is possible with this process to obtain
high-quality bisphenol A stably from phenol-containing bisphenol A.