A halogenated aromatic monomer-metal complex useful for preparing a
polymer for electronic devices such as a light-emitting diode (LED)
device is described. The aromatic monomer-metal complex is designed to
include a linking group that disrupts conjugation, thereby advantageously
reducing or preventing electron delocalization between the aromatic
monomer fragment and the metal complex fragment. Disruption of
conjugation is often desirable to preserve the phosphorescent emission
properties of the metal complex in a polymer formed from the aromatic
monomer-metal complex. The resultant conjugated electroluminescent
polymer has precisely controlled metal complexation and electronic
properties that are substantially or completely independent of those of
the polymer backbone.