The present invention discloses an acrylate nanocomposite material which can apply to optoelectronic device encapsulation, dental restorations and light waveguide. The acrylate nanocomposite material comprises an inorganic nano-particle, an acrylate monomer with at least one acrylate group, an imidized acrylate oligomer and a photo-initiator. The acrylate nanocomposite material photopolymerizes to form an organic/inorganic 3D network wherein the absorption (%) is 0.01 to 5.00 and the permeability (g mm/m.sup.2 day) is 0.01 to 10.00 thereof. In addition, the transmittance of the nanocomposite is over 90%.