Apparatus and methods for enhanced electrocoagulation processing using enhanced membrane aeration are disclosed for effluent treatment. The apparatus has an enrichment means for establishing an ion rich air/gas stream and a membrane aerator for receiving the ionized air/gas stream and effluent to be treated. An ionized air/gas rich effluent feed stream flows out of the membrane aerator and is received at an electrocoagulation processing assembly for diffused ion enhanced electrocoagulation treatment.